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sans-serif;">鈣鈦礦太陽(yáng)能電池（PSCs）自2009年報(bào)導(dǎo)以來(lái)，由于其高效能、低成本和簡(jiǎn)單制備工藝迅速引起了學(xué)術(shù)界和工業(yè)界的廣泛關(guān)注。其核心材料鈣鈦礦具有優(yōu)異的光電特性，如高吸光係數(shù)、長(zhǎng)載流子擴(kuò)散長(zhǎng)度和高載流子遷移率，使其成為下一代光伏技術(shù)的潛力選手。在過(guò)去十年間引發(fā)了廣泛的研究熱潮，并被認(rèn)為是最有潛力替代傳統(tǒng)硅太陽(yáng)能電池的下一代光伏技術(shù)之一。近年來(lái)，鈣鈦礦太陽(yáng)能電池（PSCs）的效率不斷提升，并在 NREL 的效率認(rèn)證數(shù)據(jù)中屢創(chuàng)新高。</span></p><p style="margin-top:auto;margin-bottom:auto;line-height:normal"><span style="font-size: 16px;"><span style="font-family: 新細(xì)明體, serif;"><br/></span></span></p><p style="margin-top:auto;margin-bottom:auto;line-height:normal"><span style="font-size: 16px;"><span style="font-family: 新細(xì)明體, serif;">疊層結(jié)構(gòu)的出現(xiàn)自</span>2017<span style="font-family: 新細(xì)明體, serif;">開(kāi)始，</span><span style="font-family: 微軟正黑體, sans-serif;">在過(guò)去三年中，鈣鈦礦/晶硅疊層太陽(yáng)能電池的效率取得顯著的突破。以下是一些重要的突破及其學(xué)術(shù)研究團(tuán)隊(duì)：</span></span></p><p style="margin-top:auto;margin-bottom:auto;line-height:normal"><span style="font-family: 微軟正黑體, sans-serif; font-size: 16px;">Longi綠能科技公司 (2023年)：效率：33.9%，該效率突破由NREL認(rèn)證，是當(dāng)前世界紀(jì)錄。</span><span style="font-size:13px;font-family:'微軟正黑體',sans-serif"> </span></p><p style="margin-top:auto;margin-bottom:auto;line-height:normal"><span style="font-size:13px;font-family:'微軟正黑體',sans-serif"> </span></p><p style="margin-top:auto;margin-bottom:auto;line-height:normal"><span style="font-family: 微軟正黑體, sans-serif; font-size: 16px;">沙特阿拉伯國(guó)王阿卜杜拉科技大學(xué) (KAUST) (2023年)：效率：33.7%，KAUST在2023年6月宣佈其鈣鈦礦/晶硅疊層太陽(yáng)能電池效率達(dá)到33.7%。 </span></p><p style="margin-bottom: auto; line-height: normal; margin-top: 10px;"><span style="font-family: 微軟正黑體, sans-serif; font-size: 16px;">以上資料來(lái)源參考: 美國(guó)國(guó)家可再生能源實(shí)驗(yàn)室 (NREL)</span><br/></p><p style="margin-top:auto;margin-bottom:auto;line-height:normal"><span style="font-family:'微軟正黑體',sans-serif"> </span></p><p style="margin-top:auto;margin-bottom:auto;line-height:normal"><span style="font-family: 微軟正黑體, sans-serif; font-size: 16px;"><br/></span></p><p style="margin-top:auto;margin-bottom:auto;line-height:normal"><span style="font-family: 微軟正黑體, sans-serif; font-size: 16px;">鈣鈦礦/晶硅疊層太陽(yáng)能電池，更是被認(rèn)為是未來(lái)實(shí)現(xiàn)更高效率和更低成本的理想方案。然而，在空氣環(huán)境下實(shí)現(xiàn)寬帶隙鈣鈦礦 (~1.68 eV) 的可擴(kuò)展制備一直是一個(gè)巨大的挑戰(zhàn)，因?yàn)樗謺?huì)加速鈣鈦礦薄膜的降解。</span></p><p style="margin-top:auto;margin-bottom:auto;line-height:normal"><span style="font-family: 微軟正黑體, sans-serif; font-size: 16px;"><br/></span></p><p style="margin-top:auto;margin-bottom:auto;line-height:normal"><span style="font-family: 微軟正黑體, sans-serif; font-size: 16px;">南京大學(xué)譚海仁教授團(tuán)隊(duì)近期取得重大突破，他們?cè)谘芯恐邪l(fā)現(xiàn)，溶劑的性質(zhì)對(duì)水分干擾的影響程度至關(guān)重要。通過(guò)深入研究，他們發(fā)現(xiàn)正丁醇 (nBA) 由于其低極性和中等揮發(fā)速率，不僅可以有效緩解空氣環(huán)境中水分對(duì)鈣鈦礦薄膜的負(fù)面影響，還可以提高鈣鈦礦薄膜的均勻性，進(jìn)而實(shí)現(xiàn)可擴(kuò)展制備。</span></p><p><span style="font-size: 16px;"><strong><span style="font-family: 微軟正黑體, sans-serif;"><br/></span></strong></span></p><p><span style="font-size: 16px;"><strong><span style="font-family: 微軟正黑體, sans-serif;">突破性的研究成果</span></strong></span><strong></strong></p><p style="margin-top: 10px;"><span style="font-family: 微軟正黑體, sans-serif; font-size: 16px;">利用正丁醇 (nBA) 的優(yōu)勢(shì)，譚海仁教授團(tuán)隊(duì)成功在空氣環(huán)境下製備了高性能的寬帶隙鈣鈦礦薄膜，并將其應(yīng)用于鈣鈦礦/晶硅疊層太陽(yáng)能電池。該團(tuán)隊(duì)最終實(shí)現(xiàn)了令人印象深刻的效率：</span></p><p><span style="font-family: 微軟正黑體, sans-serif; font-size: 16px;">雙面紋理化鈣鈦礦/晶硅疊層太陽(yáng)能電池，採(cǎi)用大尺寸金字塔結(jié)構(gòu) (2-3 微米)，效率達(dá)到 29.4% (經(jīng)認(rèn)證為 28.7%)。</span></p><p><span style="font-family: 微軟正黑體, sans-serif; font-size: 16px;">16 平方厘米的開(kāi)孔面積，效率達(dá)到 26.3%。</span></p><p><strong><span style="font-family:'微軟正黑體',sans-serif"> </span></strong></p><p><span style="font-size: 16px;"><strong><br/></strong></span></p><p><span style="font-size: 16px;"><strong>Enlitech </strong><strong><span style="font-family: 新細(xì)明體, serif;">設(shè)備的助力</span></strong></span><strong></strong></p><p style="margin-top: 10px;"><span style="font-size: 16px;"><span style="font-family: 新細(xì)明體, serif;">譚海仁教授團(tuán)隊(duì)在研究中使用了光焱科技</span> (Enlitech) <span style="font-family: 新細(xì)明體, serif;">的</span> QE-R <span style="font-family: 新細(xì)明體, serif;">光伏</span>/<span style="font-family: 新細(xì)明體, serif;">太陽(yáng)能電池量子效率量測(cè)方案</span> <span style="font-family: 新細(xì)明體, serif;">和</span> SS-X <span style="font-family: 新細(xì)明體, serif;">系列太陽(yáng)光模擬器，這兩款設(shè)備在鈣鈦礦太陽(yáng)能電池的性能測(cè)試和評(píng)估中發(fā)揮了至關(guān)重要的作用。</span></span></p><p style="margin-left:24px"><span style="font-size: 16px;"><span style="font-family: Wingdings;">l</span>QE-R <span style="font-family: 新細(xì)明體, serif;">光伏</span>/<span style="font-family: 新細(xì)明體, serif;">太陽(yáng)能電池量子效率量測(cè)方案可以測(cè)量不同波長(zhǎng)光照下器件的外部量子效率</span> (EQE)<span style="font-family: 新細(xì)明體, serif;">，幫助研究人員分析光電轉(zhuǎn)換過(guò)程，優(yōu)化器件結(jié)構(gòu)和材料選擇。該設(shè)備能夠提供關(guān)于器件在不同波長(zhǎng)下光電轉(zhuǎn)換效率的信息，幫助研究人員深入了解材料的光電特性，并優(yōu)化器件設(shè)計(jì)，提高能量轉(zhuǎn)換效率。</span></span></p><p style="margin-left:24px"><span style="font-size: 16px;"><span style="line-height: 115%; font-family: Wingdings;">l</span>SS-X <span style="font-family: 新細(xì)明體, serif;">系列</span> AM1.5G<span style="font-family: 新細(xì)明體, serif;">太陽(yáng)光模擬器可以精確模擬太陽(yáng)光譜，為鈣鈦礦太陽(yáng)能電池提供真實(shí)的測(cè)試環(huán)境，確保測(cè)試結(jié)果的準(zhǔn)確性和可靠性。該設(shè)備模擬光譜的精度和穩(wěn)定性，對(duì)于準(zhǔn)確評(píng)估鈣鈦礦太陽(yáng)能電池的性能至關(guān)重要。</span></span></p><p style="margin-left:24px"><span style="font-size:19px;line-height:115%"> </span></p><p><span style="line-height: 115%; font-family: 新細(xì)明體, serif; font-size: 16px;"><br/></span></p><p><span style="line-height: 115%; font-family: 新細(xì)明體, serif; font-size: 16px;">未來(lái)展望</span></p><p><span style="line-height: 115%; font-family: 新細(xì)明體, serif; font-size: 16px;"><br/></span></p><p><span style="font-size: 16px;"><span style="line-height: 115%; font-family: 新細(xì)明體, serif;">未來(lái)可能運(yùn)用的領(lǐng)域</span> </span></p><p class="MsoListParagraph" style="margin-left:24px"><span style="font-size: 16px;"><span style="font-family: Wingdings;">l</span><span style="font-family: 新細(xì)明體, serif;">建筑整合光伏（</span>BIPV<span style="font-family: 新細(xì)明體, serif;">）</span>: <span style="font-family: 新細(xì)明體, serif;">提供可觀的電力輸出，同時(shí)兼具美觀和功能性。</span></span></p><p style="margin-left:24px"><span style="font-size: 16px;"><span style="font-family: Wingdings;">l</span><span style="font-family: 新細(xì)明體, serif;">移動(dòng)裝置：其輕薄和高效能，疊層鈣鈦礦太陽(yáng)能電池可以用于移動(dòng)裝置如智能手機(jī)、筆記本電腦和無(wú)人機(jī)等，提供持久的電力支持。</span></span> </p><p style="margin-left:24px"><span style="font-size: 16px;"><span style="font-family: Wingdings;">l</span><span style="font-family: 新細(xì)明體, serif;">大規(guī)模電力生產(chǎn)：有望在大規(guī)模光伏電站中應(yīng)用，為電網(wǎng)提供穩(wěn)定的可再生能源。</span></span> </p><p style="margin-left:24px"><span style="font-size: 16px;"><span style="font-family: Wingdings;">l</span><span style="font-family: 新細(xì)明體, serif;">穿戴設(shè)備：其靈活性和高效能，可以為智能手錶和其他可穿戴設(shè)備提供持續(xù)的電力來(lái)源。</span></span></p><p style="margin-top: 15px;"><span style="font-size: 16px;"><span style="font-family: 新細(xì)明體, serif;">譚海仁教授團(tuán)隊(duì)的突破性研究成果，為鈣鈦礦</span>/<span style="font-family: 新細(xì)明體, serif;">晶硅疊層太陽(yáng)能電池的大規(guī)模生產(chǎn)開(kāi)闢了新的道路，也標(biāo)志著該技術(shù)朝著商業(yè)化應(yīng)用邁出了重要一步。未來(lái)，研究人員將繼續(xù)探索更有效的材料和工藝，進(jìn)一步提高鈣鈦礦</span>/<span style="font-family: 新細(xì)明體, serif;">硅串聯(lián)太陽(yáng)能電池的效率和穩(wěn)定性，推動(dòng)該技術(shù)成為下一代光伏技術(shù)的核心力量。</span></span></p><p><span> </span></p><p><span><br/><img src="https://img47.chem17.com/9/20240620/638544974058500921604.png" title="2.png" alt="2.png"/></span></p><p><span>Fig S15. </span><span style="font-family:'新細(xì)明體',serif">顯示了</span><span> 8 </span><span style="font-family:'新細(xì)明體',serif">個(gè)獨(dú)立的</span><span> 0.049 cm2 </span><span style="font-family:'新細(xì)明體',serif">鈣鈦礦太陽(yáng)能電池的</span><span> EQE </span><span style="font-family:'新細(xì)明體',serif">光譜。展示了不同器件的</span><span> EQE </span><span style="font-family:'新細(xì)明體',serif">特性。</span></p><p><span><br/></span></p><p><img src="https://img45.chem17.com/9/20240620/638544974166630047633.png" title="3.png" alt="3.png"/></p><p><span>Fig S17. </span><span style="font-family:'新細(xì)明體',serif">顯示了器件</span><span> (1.044 cm2 </span><span style="font-family:'新細(xì)明體',serif">開(kāi)孔面積</span><span>) </span><span style="font-family:'新細(xì)明體',serif">的</span><span> J-V </span><span style="font-family:'新細(xì)明體',serif">曲線。展示了器件的電流</span><span>-</span><span style="font-family:'新細(xì)明體',serif">電壓特性。</span></p><p><span><br/></span></p><p><span><img src="https://img45.chem17.com/9/20240620/638544974265229058183.png" title="4.png" alt="4.png"/></span></p><p><span> Fig S22. </span><span style="font-family:'新細(xì)明體',serif">顯示了具有較厚鈣鈦礦層的器件的</span><span> J-V </span><span style="font-family:'新細(xì)明體',serif">曲線。展示了器件的電流</span><span>-</span><span style="font-family:'新細(xì)明體',serif">電壓特性。</span></p><p><span><br/></span></p><p><span><img src="https://img54.chem17.com/9/20240620/638544974370141996184.png" title="5.png" alt="5.png"/></span></p><p><span> Fig. S23 </span><span style="font-family:'新細(xì)明體',serif">顯示了具有較厚鈣鈦礦層的器件的</span><span> EQE </span><span style="font-family:'新細(xì)明體',serif">曲線。展示了器件的外部量子效率特性。</span></p><p><span><br/></span></p><p><span><img src="https://img46.chem17.com/9/20240620/638544974494421920883.png" title="6.png" alt="6.png"/></span></p><p><span> Fig. S32 </span><span style="font-family:'新細(xì)明體',serif">顯示了具有和沒(méi)有鈣鈦礦過(guò)濾器的紋理化硅異質(zhì)結(jié)的</span><span> J-V </span><span style="font-family:'新細(xì)明體',serif">曲線。展示了鈣鈦礦過(guò)濾器對(duì)器件性能的影響。</span></p><p><span><br/></span></p><p><span><img src="https://img45.chem17.com/9/20240620/638544974623986284758.png" title="7.png" alt="7.png"/></span></p><p><span> Fig. S37 </span><span style="font-family:'新細(xì)明體',serif">顯示了</span><span> (a) </span><span style="font-family:'新細(xì)明體',serif">鈣鈦礦</span><span>/</span><span style="font-family:'新細(xì)明體',serif">硅串聯(lián)太陽(yáng)能電池的圖像，以及</span><span> (b) </span><span style="font-family:'新細(xì)明體',serif">刮刀涂佈的紋理化單片式鈣鈦礦</span><span>/SHJ </span><span style="font-family:'新細(xì)明體',serif">串聯(lián)電池</span><span> (16 cm2) </span><span style="font-family:'新細(xì)明體',serif">在不同位置的</span><span> EQE </span><span style="font-family:'新細(xì)明體',serif">光譜。</span></p><p><span><br/></span></p><p><span><img src="https://img43.chem17.com/9/20240620/638544974737934271327.png" title="8.png" alt="8.png"/></span></p><p><span> Fig. S42 </span><span style="font-family:'新細(xì)明體',serif">顯示了鈣鈦礦</span><span>/</span><span style="font-family:'新細(xì)明體',serif">硅串聯(lián)太陽(yáng)能電池</span><span> (16 cm2) </span><span style="font-family:'新細(xì)明體',serif">的</span><span> J-V </span><span style="font-family:'新細(xì)明體',serif">曲線。</span></p><p><strong><span style="font-size:13px;line-height: 115%;font-family:'新細(xì)明體',serif;color:#E97132"><br/></span></strong></p><p><span style="font-size: 18px;"><strong><span style="line-height: 115%; font-family: 新細(xì)明體, serif; color: rgb(233, 113, 50);">本參數(shù)采用光焱科技</span></strong><strong><span style="line-height: 115%; color: rgb(233, 113, 50);">QE-R </span></strong><strong><span style="line-height: 115%; font-family: 新細(xì)明體, serif; color: rgb(233, 113, 50);">光伏</span></strong><strong><span style="line-height: 115%; color: rgb(233, 113, 50);"> / </span></strong><strong><span style="line-height: 115%; font-family: 新細(xì)明體, serif; color: rgb(233, 113, 50);">太陽(yáng)能電池量子效率測(cè)量解決方案及</span></strong><strong><span style="line-height: 115%; color: rgb(233, 113, 50);">SS-X </span></strong><strong><span style="line-height: 115%; font-family: 新細(xì)明體, serif; color: rgb(233, 113, 50);">系列</span></strong><strong><span style="line-height: 115%; color: rgb(233, 113, 50);">AM1.5G </span></strong><strong><span style="line-height: 115%; font-family: 新細(xì)明體, serif; color: rgb(233, 113, 50);">標(biāo)準(zhǔn)光譜太陽(yáng)光模擬器</span></strong><strong></strong></span></p><p><strong><span style="font-size:13px;line-height:115%;font-family:'新細(xì)明體',serif;color:#E97132"><br/></span></strong></p><p><img src="https://img45.chem17.com/9/20240620/638544974852304449550.png" title="9.png" alt="9.png"/></p><p><img src="https://img42.chem17.com/9/20240620/638544974935320446585.png" title="10.png" alt="10.png"/></p><p><span> <img src="https://img45.chem17.com/9/20240620/638544975017128342490.png" title="11.png" alt="11.png"/></span></p><p><span> </span></p><p><span style="font-size: 18px;"><span style="font-family: 新細(xì)明體, serif;"><br/></span></span></p><p><span style="font-size: 18px;"><span style="font-family: 新細(xì)明體, serif;">參考文獻(xiàn)</span>: <span style="line-height: 115%;">Solvent engineering for scalable fabrication of perovskite/silicon tandem solar cells in air. </span><strong><i><span style="line-height: 115%; font-family: Roboto; color: rgb(38, 38, 38);">nature communications</span></i></strong></span></p><p><span> </span></p><p><span> </span><span style="background-color: white;"> </span></p><p style=";background:white"><span> </span></p><p style=";background:white"><span> </span></p><p style=";background:white"><span style="font-size: 16px;"><span style="font-family: 新細(xì)明體, serif;"><br/></span></span></p><p style=";background:white"><span style="font-size: 16px;"><span style="font-family: 新細(xì)明體, serif;"><br/></span></span></p><p style=";background:white"><span style="font-size: 16px;"><span style="font-family: 新細(xì)明體, serif;"><br/></span></span></p><p style=";background:white"><span style="font-size: 16px;"><span style="font-family: 新細(xì)明體, serif;">推薦設(shè)備</span>_</span><span> </span></p><p style="margin-left:24px"><span style="font-size: 16px;">1.<span style="font-variant-numeric: normal; font-variant-east-asian: normal; font-variant-alternates: normal; font-kerning: auto; font-optical-sizing: auto; font-feature-settings: normal; font-variation-settings: normal; font-variant-position: normal; font-stretch: normal; line-height: normal; font-family: " times="" new=""> </span><strong>SS-PST100R AM1.5G </strong><strong><span style="font-family: 新細(xì)明體, serif;">可變標(biāo)準(zhǔn)光譜模擬光源</span></strong></span></p><p style="margin-left:24px"><strong><span><span style="font-family:新細(xì)明體, serif"><span style="font-size: 16px;"><br/></span></span></span></strong><span><img src="https://img41.chem17.com/9/20240620/638544975154761485387.png" title="12.png" alt="12.png"/> <img src="https://img43.chem17.com/9/20240620/638544975285783971863.png" title="13.png" alt="13.png"/></span></p><p style="margin-left:24px"><span style="font-family: 新細(xì)明體, serif; font-size: 16px;"><br/></span></p><p style="margin-left:24px"><span style="font-family: 新細(xì)明體, serif; font-size: 16px;">具有以下特色優(yōu)勢(shì)：</span></p><p style="margin-left:24px"><span style="font-size: 16px;"><span style="font-family: Wingdings;">l</span><span style="font-family: 新細(xì)明體, serif;">采用光焱最新的單氙燈光源光譜控制技術(shù)，可在單一氙燈光源下將光譜修飾，達(dá)到氙燈加鹵燈雙光源光譜等級(jí)。</span></span></p><p style="margin-left:24px"><span style="font-size: 16px;"><span style="font-family: Wingdings;">l</span><span style="font-family: 新細(xì)明體, serif;">輸出光譜由</span> 300-1700nm <span style="font-family: 新細(xì)明體, serif;">均可符合</span> 1.5G <span style="font-family: 新細(xì)明體, serif;">光譜要求其平均光譜失配</span> ≤ 6% (IEC 60904-9<span style="font-family: 新細(xì)明體, serif;">：</span>2020) <span style="font-family: 新細(xì)明體, serif;">。</span></span></p><p style="margin-left:24px"><span style="font-size: 16px;"><span style="font-family: Wingdings;">l</span><span style="font-family: 新細(xì)明體, serif;">僅采用單氙燈，因此無(wú)雙光源兩燈泡壽命不匹配，以及一般鹵燈僅</span> 50 <span style="font-family: 新細(xì)明體, serif;">小時(shí)壽命之問(wèn)題。</span></span></p><p style="margin-left:24px"><span style="font-size: 16px;"><span style="font-family: Wingdings;">l</span><span style="font-family: 新細(xì)明體, serif;">具有</span>A++<span style="font-family: 新細(xì)明體, serif;">光譜等級(jí)，其氙燈壽命可超過(guò)</span>1,000<span style="font-family: 新細(xì)明體, serif;">小時(shí)，克服了雙光源鹵素?zé)魺襞輭勖坏?/span>50<span style="font-family: 新細(xì)明體, serif;">小時(shí)之缺點(diǎn)。</span></span></p><p style="margin-left:24px"><span style="font-size: 16px;"><span style="font-family: Wingdings;">l</span><span style="font-family: 新細(xì)明體, serif;">大幅縮減光源調(diào)校時(shí)間，并增加系統(tǒng)測(cè)試結(jié)果的數(shù)據(jù)重現(xiàn)性。</span></span></p><p style="margin-top: 10px;"><span style="font-size: 16px;"><span style="line-height: 115%; font-family: 新細(xì)明體, serif;">單燈源的設(shè)計(jì)，相較多燈珠</span><span style="line-height: 115%; font-family: Aptos, sans-serif;"> LED </span><span style="line-height: 115%; font-family: 新細(xì)明體, serif;">型的模擬器有更好的</span><span style="line-height: 115%; font-family: Aptos, sans-serif;"> SPC </span><span style="line-height: 115%; font-family: 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